青铜文物腐蚀过程中的次生矿物   总被引：3，自引：0，他引：3  

陈璋如  刘月妙  范光  孙淑云  李延祥 《矿物岩石》2004,24(1):10-13

产于不同环境不同地方的青铜文物经矿相显微镜观察、电子探针成分分析和X射线衍射研究表明，在青铜文物腐蚀层中观察到次生矿物——赤铜矿、孔雀石、蓝铜矿、白铅矿和锡石。由上述矿物组成的腐蚀层在青铜器表面形成保护层。腐蚀层细分为红色赤铜矿层、绿色碳酸盐矿物层和黄色锡石层组成，其厚度小于1mm。青铜合金在潮湿条件下的腐蚀比在干旱条件下要严重，另外青铜合金是适用于作高放废物地质处置系统中的废物罐的候选材质。  相似文献   

The Influence of Oxalate on Fe-Catalyzed S(IV) Oxidation by Oxygen in Aqueous Solution     

A. Wolf  F. Deutsch  P. Hoffmann  H. M. Ortner 《Journal of Atmospheric Chemistry》2000,37(2):125-135

This study demonstrates that oxalate has a strong inhibiting effect onFe-catalyzed S(IV) oxidation by oxygen in aqueous solution. While thepseudo-first order rate constant of S(IV) oxidation was determined to be1.6 × 10³ M^-1 s^-1 in experimentswithout oxalate, the oxidation of S(IV) was totally inhibited at a molarconcentration ratio of iron:oxalate = 1:5 at an oxalate concentration of 4M. Under these conditions, the Fe(II)/Fe(III) ratio remained nearlyconstant during the observed reaction time. The determined rate constants wereindependent of the initial oxidation state of iron. However, with increasingconcentrations of oxalate, a longer induction period is observed forexperiments with iron initially in the Fe(II) oxidation state.  相似文献   

腾冲地热水化学特征及腐蚀机理探讨   总被引：5，自引：0，他引：5  

符必昌  方丽萍 《水文地质工程地质》1998,25(3):1-3,8

本文从腾冲地热成因的角度,分析其地热水化学的总体特征和赋存规律。在此基础上对地热水ｐＨ值、流速、溶解氧、ＣＯ２及Ｃｌ＾－、ＳＯ４＾２－、ＳｉＯ３＾２－、Ｃａ＾２等对金属材料的腐蚀机理进行讨论。  相似文献   

Reform of Carbonate Rock Subsurface by Crustose Lichens and Its Environmental Significance   总被引：5，自引：0，他引：5  

CAO Jianhua  WANG FuxingInstitute of Karst Geology  Chinese Academy of Geological Sciences  Guilin  Guanxi Xiao Pinfang Liu Xinzhu 《《地质学报》英文版》1998,72(1):94-99

Crustose lichens are distributed extensively in karst areas in Southern China. They can be found on the surface of carbonate rocks. Through biophysical and biochemical processes, crustose lichens reform the subsurface of carbonate rocks and in the meanwhile change their physical and chemical properties: (1) the mechanical strength decreases by 17.04° on average (up to 33.2° ); (2) the chemical solution surface area increases from 28.26% to 75.36% (lichen microholes considered only); and (3) the water-holding capacity is greatly improved. Comparative field experiments between biokarst samples underneath crustose lichens and fresh rock samples with the same composition and texture show that the corrosional rate of carbonate rocks of the former is 1.264-1.643 times higher than that of the latter. Crustose lichens are considered as an activator of the surface corrosion of carbonate rocks.  相似文献   

环境水土对重要建筑材料的腐蚀作用     

梅祖明 《上海国土资源》1998,(4):53-57

从建筑材料和水土中活跃成分的化学性质出发,讨论环境水土成分对重要建筑材料的腐蚀的机理及其评价的有关问题。  相似文献   

Impedance characteristics of carbon steel under cathodic protection   总被引：1，自引：0，他引：1  

李言涛  侯保荣 《中国海洋湖沼学报》1998,16(1):60-63

INTRODUCTIONInpraCticalengineeringapplicati0ns,thecormsionofstalundercathodicprotalioncanbecontr0llediftheproodi0np0tenhalisset2O()t03(X)mVnegativewithaspeCttothenatamlcormsi0np0tenial(MasatSugi,l976,Takehiko,l972).Theprotalnp0tentia1edinpraedcalapplicationisbedonexperienceandtheory.Tooru(l985,l986)foundthattheopbocathodicproodionpotentialcoinddedwiththepotentialwhenpolarhati0nresistancemaxndnd,s0thiscoinedencecanbeedt00btainoptbore-sultforcarbonstalundercathodicpronaion.Inthiswork,the…  相似文献   

ELECTROCHEMICAL MEASUREMENT OF STEEL CORROSION IN SEABOTTOM SEDIMENT WITH “MD” METHOD     

马士德  李言涛  谢肖勃  郑国安  常伟  栗艳侠 《中国海洋湖沼学报》1996,(2)

The tbough one year cormsion potential and polarisation resistanoc for 3 kinds of stals in seabottomedment of Liaodong Bay were measured with the “MD” method.The measurements wiIl have some thoretical and pndital talues. The thooretical valoc lies in thatthe reoorded changing process of the practital corrosion case can be basis for indoor discussion andeectrochemical on the corrosion practical value lies in that the obtained datu canbe basis for designing and controlling elatrochemical protation syttems. In fact, it is very difficult tomeasure in situ the cornosion parnders of steeIs in sea sediment.  相似文献   

Electrochemical corrosion behavior of hot dip coating in artificial seawater     

孙虎元  侯保荣  马士德  魏绪钧 《中国海洋湖沼学报》1999,17(2):181-186

INTR0DUCnONAlloycoatingscandetivelyproteCtsteelagainstcormsioninseri0uscormsionenvir-orunent,suchasthedrinesplashandtidalzones-TwoInainhodiptincaldrinumalloycOaingswidelyusedcommroiallyareGalfancoaing(contalningZn-5wt%kl-us)devel-oPedbytheIntemaionaltalZincReenhheZaionandhocoating(c0n-talningZn-55Wt%Al-1.6Wt%Si)develoPedbytheBethlehemSteelCorpOration-Anewrinc-basedalloycOaingdevel0PedbyNortheaStemUniversityisdiscussedinthesPaperbyelecthehendcalmethod.FromSun(l996),welmOWthecorms…  相似文献   

Al_2O_3-SiC-C砖渣静态侵蚀后的显微结构分析     

李继铮  徐国涛  杜鹤桂 《矿物岩石地球化学通报》1999,(4)

铁水预处理用鱼雷罐、铁水罐的炉衬多为Ａｌ２Ｏ３ＳｉＣＣ砖,随着铁水脱硫量的加大,耐火材料的侵蚀也较严重。而现在由于市场需要钢水中的磷含量要求较低,脱磷处理过程中由于国外多采用氧化铁系脱磷剂,氧化亚铁对石墨的氧化很大,对炉衬侵蚀也大,这就要求对Ａｌ２Ｏ３ＳｉＣＣ砖的性能进行改进以适宜工艺需要。国内对脱磷的研究较少,实际生产对铁水进行脱磷处理的厂家也很少。为探讨脱硫、磷剂对耐火材料的影响,本文对不同脱硫、磷剂侵蚀Ａｌ２Ｏ３ＳｉＣＣ砖后的残砖的显微结构进行了分析,探讨了铝碳化硅碳砖的侵蚀原…  相似文献   

滨海岩溶区过渡带碳酸盐岩溶浊作用的试验研究   总被引：3，自引：0，他引：3  

邹胜章  陈鸿汉  朱远峰  刘菲 《水文地质工程地质》2001,28(5):17-20

滨海岩溶具有内陆一般岩溶区不同的发育机理，其过渡带混合溶蚀作用是控制滨海岩溶发育的最主要因素之一。通过七组不同淡水与海水配比的混合溶蚀实验（封闭CO2－H2O系统），初步得出了过渡带混合溶蚀作用的基本结论：（1）滨海岩溶区过渡带岩溶发育的基本规律与内陆一般岩溶区岩溶发育规律的基本一致，即岩性，结构是控制滨海岩溶发育的最主要因素；（2）滨海岩溶区混合过渡带内碳酸盐岩的混合溶蚀速率大于纯淡水或纯海水中同种岩石的溶蚀速率；（3）在不同的CO2分压条件下，滨海岩溶区混合过渡带内碳酸盐岩的混合溶蚀机理不同。  相似文献